next up previous
Next: and Other Quantities Up: RESULTS Previous: Hybrid Models

from Neutron Diffraction Studies

Our main result that bilayer structure does not change with mild dehydration down to suggests that the older neutron diffraction results (Buldt et al., 1979) which were obtained for , should be valid for fully hydrated phase DPPC. We here show two ways that those results can be used to obtain . The first way to use the neutron results employs Eq. 7, but instead of using electron densities to obtain , the differences in the locations of various molecular groups between the fully hydrated gel and phases are used. The headgroup labels at the , and positions yield 2.6, 2.9 and 2.6 Å, respectively. The hydrocarbon chain labelled at the position yields Å. Only the glycerol label GC3 is out of line with Å. Discounting this latter result and averaging the other values gives Å and a value Å using Eq. 7. The second way uses the results for the positions of the 4th and 5th methylenes, Å and Å (although it may be noted that these two spacings are mutually inconsistent because their difference exceeds the C-C bond length of 1.54Å). We take the average spacing of 11.4Å to include, on average, all the methylenes with carbon number 5 or greater and all the terminal methyls. Assuming that the volume of each terminal methyl is twice the volume of each methylene, one has

 

where Å (Nagle and Wiener, 1988).



This document was converted to HTML by Nikolai Gouliaev on Fri Oct 4 15:28:39 EDT 1996
Your comments are welcome at gouliaev@andrew.cmu.edu